Use of AlPO-11, SnAPO-11, SAPO-31 and SAPO-41 Elaborated Solid Materials as Catalysts in Ammonia Alkylation Reaction
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چکیده
منابع مشابه
Methylation of Naphthalene with Methanol over SAPO-11 Zeolite
Shape-selective methylation of naphthalene (NAPH) over SAPO-11 zeolite was carried out in a fixed-bed flow reactor under atmospheric pressure. Some zeolites, such as H-beta (Hβ), HUSY and ZSM-5 were also evaluated for comparison with SAPO-11 zeolite.The results showed that SAPO-11 exhibited higher stability, higher selectivity of 2,6-dimethylnaphthalene (2,6-DMN), and higher 2,6-/2,7-DMN r...
متن کاملCharacterization and optimization of SAPO-34 catalysts synthesized by mixed templates in MTO reaction
"> The effects of templating on the catalytic performance of SAPO-34 catalyst have been investigated in conversion of methanol to olefins. SAPO-34 <span style="font-size: 11pt; color: #000000; font-sty...
متن کاملTheoretical study of small clusters Au_{3-4} on Au/SAPO-11 catalysts and their interactions with CO
Quantum chemistry calculations were done, using the ONIOM2 methodology at two different levels of calculation, B3LYP for the high level and UFF for the low level. These calculations were performed on Au3/SAPO-11, Au4/SAPO-11, CO-Au3/SAPO-11 and CO-Au4/SAPO-11 aggregates to analyze the geometries of small clusters of Au3 and Au4 on SAPO-11 support. Au3 cluster present a triangle structure in Au3...
متن کاملSynthesis of SAPO-34 catalysts via controlled crystal growth
Introduction SAPO-34 is a silicoaluminophosphate zeolite with 8-membered ring windows (~0.38nm) displaying chabazite structure. SAPO-34 is an efficient catalyst showing improved catalytic performance in reactions such as methanol conversion to olefins [1], oxidative dehydrogenation of propane [2], conversion of light alkenes [3]. Its catalytic properties are mainly attributed to its mild acidit...
متن کاملmethylation of naphthalene with methanol over sapo-11 zeolite
shape-selective methylation of naphthalene (naph) over sapo-11 zeolite was carried out in a fixed-bed flow reactor under atmospheric pressure. some zeolites, such as h-beta (hβ), husy and zsm-5 were also evaluated for comparison with sapo-11 zeolite.the results showed that sapo-11 exhibited higher stability, higher selectivity of 2,6-dimethylnaphthalene (2,6-dmn), and higher 2,6-/2,7-dmn ratio...
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ژورنال
عنوان ژورنال: Journal of Applied Sciences
سال: 2007
ISSN: 1812-5654
DOI: 10.3923/jas.2007.2371.2375